Synthetic approaches to a fluorinated tetrahedrane
Abstract
Approaches to tetrakis(2-chlorotetrafluoroethyl)tetrahedrane ( 2) from 1,6-dichlorooctafluoro-3-hexyne ( 4) have been explored. The synthesis and chemistry are described of cyclopropenyl ketenimines ( 6a, b), a Dewar thiophene ( 24) and a cyclobutadienetricarbonyliron complex ( 33) derived from this acetylene.
- Publication:
-
Journal of Fluorine Chemistry
- Pub Date:
- January 2000
- DOI:
- Bibcode:
- 2000JFluC.102..323S
- Keywords:
-
- Tetrahedrane;
- Cyclobutadiene;
- Dewar thiophene;
- Cyclopropenyl ketenimines