Relative mixing coefficients of zero-order 1B1(n,0,0) levels in the 1B1-1A2 hybrid wave functions of the vibronic bands of SO2 in the 32 184-34 040 cm-1 region
Abstract
The relative mixing coefficients of the zero-order 1B1(n,0,0) vibrational levels present in the hybrid 1A2-1B1 wave functions are estimated according to the observed Franck-Condon patterns in dispersed fluorescence spectra. Non-Condon effects and spin-orbit coupling have been ignored in the treatment. The data cover nearly 50 cold vibronic bands in the 32 895-34 040 cm-1 region in addition to 9 vibronic bands in the 32 185-32 559 cm-1 region.
- Publication:
-
Journal of Chemical Physics
- Pub Date:
- July 1999
- DOI:
- 10.1063/1.479441
- Bibcode:
- 1999JChPh.111.1784D
- Keywords:
-
- 33.50.Dq;
- 33.20.Wr;
- 33.70.Ca;
- Fluorescence and phosphorescence spectra;
- Vibronic rovibronic and rotation-electron-spin interactions;
- Oscillator and band strengths lifetimes transition moments and Franck-Condon factors