Calibrated measurements of the isotopic composition and atomic weight of the natural Li isotopic reference material IRMM-016
Abstract
The isotope abundance ratio of lithium in the Li isotopic reference material IRMM-016 was redetermined by thermal ionisation mass spectrometry by means of synthetic isotope mixtures. This resulted in an absolute ratio n(6Li)/n(7Li) of 0.08212 +/- 0.00028, and corresponding isotope abundances of 7.589 +/- 0.024 amount % 6Li, 92.411 +/- 0.024 amount % 7Li and an atomic weight of lithium of 6.94005 +/- 0.00024. Uncertainties are expanded uncertainties using a coverage factor of two.
- Publication:
-
International Journal of Mass Spectrometry and Ion Processes
- Pub Date:
- December 1997
- DOI:
- 10.1016/S0168-1176(97)00125-0
- Bibcode:
- 1997IJMSI.171..263Q
- Keywords:
-
- Mass spectrometry;
- Isotopic composition;
- Atomic weight;
- Lithium;
- Thermal ionisation