Analytical solution of the proper integral equations for interaction site fluids
Abstract
We apply the Wiener-Hopf factorization technique to the Chandler-Silbey-Ladanyi equations with the Percus-Yevick closure for a general fluid composed of hard-sphere interaction sites. We analytically solve these equations for symmetric n-atomic tangent hard-sphere molecules (n≤4), and obtain closed analytical expressions for the equation of state and other thermodynamic properties of the fluid.
- Publication:
-
Journal of Chemical Physics
- Pub Date:
- July 1995
- DOI:
- 10.1063/1.469833
- Bibcode:
- 1995JChPh.103.1229L