Transportation of volatile elements in thermally evolving planetesimals: an important role of metallic iron
Abstract
Ordinary chondrites are considered to have experienced thermal metamorphism in small bodies. We are interested in behaviors of volatile elements in such a kind of thermally evolving planetesimals. Volatile elements generally have high vapor pressures at high temperature. In porous bodies, with a high gas permeability, volatile elements are transported efficiently over a long range. Behavior of volatile elements transported by permeable gas flow can be handled by an equation whose form is similar to that of the equation of thermal diffusion. We can follow transportation of heats and volatile elements in planetesimals, when parameters in these equations, initial conditions and chemical behavior of volatile elements are given. Recently, we discovered that nitrogen in equilibrated H-chondrites is mainly trapped in taenite (f.c.c. Fe-Ni), probably dissolved in interstitial sites. Fegley suggests that metallic iron cannot trap nitrogen in the solar nebula gas due to its very low nitrogen partial pressure. Approximately 1 bar of nitrogen pressure is required to explain the nitrogen content in taenite. We may expect high nitrogen gas partial pressure (possibly produced by vaporization of nitrogen-bearing solids such as organic materials) at the interior of thermally evolving planetesimals. Kinetic behavior of nitrogen in taenite suggests that it can easily be equilibrated with the ambient nitrogen gas at temperatures of approximately 500 C or higher. We consider that nitrogen is trapped in taenite through a nitrogen redistribution process occurred during the thermal metamorphic event.
- Publication:
-
Deep Earth and Planetary Volatiles
- Pub Date:
- 1994
- Bibcode:
- 1994depv.conf...13H
- Keywords:
-
- Chondrites;
- Gas Flow;
- High Pressure;
- High Temperature;
- Iron;
- Metamorphism (Geology);
- Nitrogen;
- Porosity;
- Protoplanets;
- Transportation;
- Vapor Pressure;
- Ambient Temperature;
- Chemical Reactions;
- Gas Pressure;
- Interstitials;
- Low Pressure;
- Partial Pressure;
- Planetary Nebulae;
- Thermal Diffusion;
- Astrophysics