Light-induced excited states in H-
Abstract
We present a nonperturbative, fully correlated calculation of the structure of H- in an intense laser field, based on the high-frequency Floquet theory. We show that, as the intensity increases at sufficiently high frequencies, the electron affinity manifests a peculiar behavior and can become substantially higher than its field-free value. Besides, H- acquires excited states, some of which are doubly excited and nonautodetaching. At high intensities H- undergoes stabilization, similarly to the H atom.
- Publication:
-
Physical Review Letters
- Pub Date:
- September 1993
- DOI:
- 10.1103/PhysRevLett.71.1693
- Bibcode:
- 1993PhRvL..71.1693M
- Keywords:
-
- Atomic Excitations;
- Floquet Theorem;
- Hydrogen Ions;
- Photoionization;
- Linear Polarization;
- Probability Density Functions;
- Schroedinger Equation;
- Atomic and Molecular Physics;
- 32.80.Rm;
- Multiphoton ionization and excitation to highly excited states