In situ stratospheric measurements of HNO3 and HCl Near 30 km using the balloon-borne laser in situ sensor tunable diode laser spectrometer
Abstract
In situ stratospheric measurements of the concentrations of the reservoir species HNO3 and HCl made during two flights of the high-resolution (0.0005 cm-1) balloon-borne laser in situ sensor (BLISS) instrument from Palestine, Texas, are reported. A measured HNO3 volume mixing ratio of 4.3 parts per billion by volume (ppbv) at 31 km altitude is about 1 ppbv larger than previously reported measurements at 32°N. An HCl mixing ratio of 1.6 ppbv at 29 km is in agreement with values obtained from earlier remote sensing techniques within the experimental uncertainties. Upper limits at 31 km of 0.4 ppbv for H2O2 and 0.2 ppbv for HOCl are also derived from analyses of spectra recorded near 1252 cm-1.
- Publication:
-
Journal of Geophysical Research
- Pub Date:
- November 1989
- DOI:
- 10.1029/JD094iD13p16343
- Bibcode:
- 1989JGR....9416343M
- Keywords:
-
- Balloon Sounding;
- Hydrochloric Acid;
- Laser Spectroscopy;
- Nitric Acid;
- Stratosphere;
- Balloon-Borne Instruments;
- Laser Applications;
- Mixing;
- Tunable Lasers;
- Atmospheric Composition and Structure: Middle atmosphere-composition and chemistry;
- Atmospheric Composition and Structure: Instruments and techniques