Cross sections for excitation of the b3Σ+u, a 3Σ+g, and c3Πu states of H2 by low-energy electrons
Abstract
We used a multichannel extension of the Schwinger variational principle [K. Takatsuka and V. McKoy, Phys. Rev. A 24, 2473 (1981)] to study the cross sections for excitation of the X 1 Σ+g-->b 3Σ+u, a 3Σ+g, and c3Πu transitions in H2 by low-energy electrons. These cross sections were obtained with two open channels for each transition and for energies near threshold to 30 eV. The results for the b3Σ+u and a 3Σ+g states agree quite well with available experimental data. However, the cross sections for excitation of the c 3Πu state differ significantly from the measured values at the two energies, 20 and 30 eV, where data are available.
- Publication:
-
Physical Review A
- Pub Date:
- November 1988
- DOI:
- 10.1103/PhysRevA.38.4527
- Bibcode:
- 1988PhRvA..38.4527L
- Keywords:
-
- Electron Scattering;
- Hydrogen;
- Molecular Energy Levels;
- Scattering Cross Sections;
- Adsorption;
- Franck-Condon Principle;
- Hamiltonian Functions;
- Molecular Orbitals;
- Variational Principles;
- Atomic and Molecular Physics;
- 34.80.Gs;
- Molecular excitation and ionization by electron impact