Energy dependent relaxation and the theory of resonance Raman scattering
Abstract
We present a ``transform'' theory for analyzing resonance Raman scattering under the condition of energy or state dependent dampibng. The energy dependence of the damping is taken to be linear in the Raman quantum but arbitrary in the remaining subspace of vibrations. The theory is tested using exact sumoverstates model calculations. The effects of truncation error are explicitly assessed. The method is applied to a Raman excitation profile of cytochrome P450, which is ``red shifted'' with respect to the resonant absorption band.
 Publication:

Journal of Chemical Physics
 Pub Date:
 January 1988
 DOI:
 10.1063/1.454154
 Bibcode:
 1988JChPh..88..761L