Airborne intercomparison of carbon monoxide measurement techniques

Results from an airborne intercomparison of techniques to measure tropospheric levels of carbon monoxide (CO) are discussed. The intercomparison was conducted as part of the National Aeronautics and Space Administration's Global Tropospheric Experiment and included a laser differential absorption method and two grab sample/gas chromatograph methods. Measurements were obtained during approximately 90 flight hours, during which the CO mixing ratios ranged from about 60 to 140 ppbv. The level of agreement observed for the ensemble of measurements was well within the overall accuracy stated for each instrument. The correlation observed between the measurements from the respective pairs of instruments ranged from 0.85 to 0.98, with no evidence for the presence of either a constant or proportional bias between any of the instruments.