Microwave processing and diagnosis of chemically reacting materials in a single-mode cavity applicator
Abstract
Online microwave processing and dielectric diagnosis of chemically reacting materials (epoxy/amine) have been successfully performed using a TM012-mode cylindrical cavity at a frequency of 2.45 GHz in conjunction with fluoroptic temperature measurement. Complex permittivity measurements by this single-frequency technique are repeatable and consistent with those obtained by conventional swept-frequency methods. The accuracy of complex permittivity measurements for both methods is within + or - 5 percent for permittivity and + or - 15 percent for loss. Both techniques are based on material-cavity perturbation theory. Perturbation equations for cylindrical shapes of the cavity and loaded material were derived to account for volume variation of the sample due to thermal expansion. Complex permittivity of epoxy/amine as a function of the extent of cure and temperature was determined in order to monitor the chemical reaction progress during microwave processing.
- Publication:
-
IEEE Transactions on Microwave Theory Techniques
- Pub Date:
- December 1987
- DOI:
- 10.1109/TMTT.1987.1133872
- Bibcode:
- 1987ITMTT..35.1435J
- Keywords:
-
- Cavity Resonators;
- Dielectrics;
- Epoxy Resins;
- Microwave Frequencies;
- Permittivity;
- Reaction Kinetics;
- Amines;
- Q Factors;
- Temperature Measurement;
- Thermal Expansion;
- Thermosetting Resins;
- Instrumentation and Photography