Synthesis and vibrational analysis of new anhydrous oxochloroperchlorato complexes of titanium IV
Abstract
Chlorine trioxide Cl 2O 6 added on an excess of TiCl 4 gives a series of anhydrous oxo-chloro-perchlorato complexes of titanium IV corresponding to the formula: Ti 6O 4Cl x(ClO 4) 16-x. x increases with the molar ratio TiCl 4: Cl 2O 6 and reaction time. Infrared and Raman spectra of these compounds are consistent with polymeric structure containing bridging bidentate perchlorato groups stongly bonded to the metal.
- Publication:
-
Journal of Molecular Structure
- Pub Date:
- March 1986
- DOI:
- 10.1016/0022-2860(86)85225-5
- Bibcode:
- 1986JMoSt.143..147F