Analysis of ν2 of H 233S and H 234S
Abstract
We have extended our analysis of the (010) vibrational state of H 2S, this time using Watson's A-reduced Hamiltonian (through P8 terms) in the I' rotational representation. We have determined separate sets of (010) upper state constants for each isotopomer (H 232S, H 233S, and H 234S) by fitting the ν2 spectral lines, keeping the ground state constants fixed to the values determined by Flaud, Camy-Peyret, and Johns. Determinable coefficients for H 232S and a slightly revised set of ν2 line assignments for H 233S and H 234S are also reported.
- Publication:
-
Journal of Molecular Spectroscopy
- Pub Date:
- June 1985
- DOI:
- 10.1016/0022-2852(85)90008-6
- Bibcode:
- 1985JMoSp.111..320L