Ionization-detected Raman studies of the 1600 cm-1 Fermi dyad of benzene
Abstract
We present the first rotationally resolved Raman spectrum of a degenerate rovibrational transition in benzene as a demonstration of the high spectral resolving power and sensitivity attainable by ionization detected stimulated Raman spectroscopy (IDSRS). The double-resonance form of the technique allows the clean separation of the Raman spectra of the Fermi dyad composed of the ν16 fundamental and ν2+ν18 combination vibrations.
- Publication:
-
Journal of Chemical Physics
- Pub Date:
- October 1985
- DOI:
- 10.1063/1.449190
- Bibcode:
- 1985JChPh..83.3311E