Hydrogeochemistry of Lake Turkana, Kenya: Mass balance and mineral reactions in an alkaline lake

Lake Turkana, in northwestern Kenya, is a closed-basin, alkaline ( pH = 9.2) lake of moderate salinity ( TDS = 2500 ppm). Principal ions are Na ⁺, HCO ^-₃ and CI ^-. The lake is essentially polymictic in the northern basin and little compositional variation occurs in surface waters. The Omo River is the principal influent, providing some 80-90% of water input to the lake. Chloride has an apparent accumulation time of about 2500 years after accounting for burial of interstitial water. The bottom sediments are predominantly detrital and fine-grained, yet mineral-water reactions are very important for the geochcmical budget. Ca ²⁺ is precipitated as calcite; Na ⁺ is removed as an exchangeable cation on smectite; Mg ²⁺ is probably incorporated into a Mg-silicate phase, most likely poorlycrystalline smectite, as it enters the lake water; K ⁺ may be used in illite regradation. Cation exchange is a very important process in the mass balance of this lake. Over 40% of incoming Na is removed as an exchangeable cation. After cation exchange and interstitial water burial, Na has a response time of 2650 years, which compares favorably with that of chloride. These processes seem to occur rapidly within the water mass of the lake: other reactions may be important in regulating interstitial water compositions. Several changes occur in the upper 3m of sediment: interstitial-water pH drops to 8.3 and alkalinity increases slightly with depth, SO ^2-₄ decreases slightly, and amorphous silica saturation is approached. These changes are a response to organic matter oxidation and the dissolution of unstable silicates rather than a reversal of reactions occurring in the lake water. High rates of sedimentation (up to 1 cm per year) may minimize the effects of diffusion between the interstitial waters and the lake water, although burial of interstitial water assumes considerable importance.