The removal of DF (v = 3 and 4) by H and D atoms
Abstract
The deactivation rate coefficients for the removal of DF(v equal 3) and DF(v equal 4) by H and D atoms have been measured at 295 K by the technique of laser-induced fluorescence in a discharge flow-tube apparatus. The rate coefficients were found to increase dramatically with vibrational level v. Data obtained for the removal of DF(v equal 4) in the presence of H atoms have been used to infer a rate coefficient of (5 plus or minus 2) x (1011 cubic centimeters/mol-s for the reaction H plus DF(v equal 4) yield HD plus F.
- Publication:
-
NASA STI/Recon Technical Report N
- Pub Date:
- April 1982
- Bibcode:
- 1982STIN...8228635B
- Keywords:
-
- Chemical Lasers;
- Deuterium Fluorides;
- Fluorescence;
- Deactivation;
- Deuterium;
- Hydrogen Atoms;
- Laser Induced Fluorescence;
- Reaction Kinetics;
- Vibrational Spectra;
- Lasers and Masers