Mo study on charge distributions in octahedral PF -6, AsF -6 and SbF -6 anions
Abstract
The charge distributions in octahedral PF -6, AsF -6, and SbF -6 anions are studied by means of the ab initio molecular orbital method. We find that the central P, As, and Sb atoms are all positively charged in these anions, while F atoms negatively charged, the order of the positive charge being Sb > P > As.
- Publication:
-
Solid State Communications
- Pub Date:
- October 1982
- DOI:
- 10.1016/0038-1098(82)90887-0
- Bibcode:
- 1982SSCom..44..431T