Synthesis and electrical properties of new chalcogenide compounds containing mixed (Mo, Me) 6 octahedral clusters ( Me = Ru or Rh)
Abstract
We report the synthesis and some properties of new compounds and some solid solutions containing mixed octahedral ( Me) 6 clusters ( Me = Mo, Ru, Rh). The compound Mo 4Ru 2Se 8 is semiconducting whereas the limit compounds Mo 4Ru 2Te 8 and Mo 4.66Rh 1.33Te 8 are metallic. Superconductivity was found around the composition Mo 5RuTe 8.
- Publication:
-
Journal of Solid State Chemistry France
- Pub Date:
- June 1980
- DOI:
- 10.1016/0022-4596(80)90547-2
- Bibcode:
- 1980JSSCh..33...43P