Vibrational level populations in the autoionization of oxygen
Abstract
Autoionization from the I and I' resonance series of O2 has been reexamined using high resolution for photons and electrons. Photoelectron spectra on the resonances are predicted from the upper potential energy surface parameters and photoionization yield curve alone, without reference to the uncertain line shapes and widths. Bond lengths are determined as 1.370±.005 Å in I and 1.380±.005 Å in I' of O2.
- Publication:
-
Journal of Chemical Physics
- Pub Date:
- June 1980
- DOI:
- 10.1063/1.439100
- Bibcode:
- 1980JChPh..72.6015E
- Keywords:
-
- Autoionization;
- Gas Ionization;
- Molecular Oscillations;
- Oxygen;
- Photoelectron Spectroscopy;
- Photoionization;
- Electronic Spectra;
- High Resolution;
- Line Shape;
- Resonant Vibration;
- Rydberg Series;
- Spectral Line Width;
- Atomic and Molecular Physics;
- 33.80.Eh;
- 33.60.Cv;
- Autoionization photoionization and photodetachment;
- Ultraviolet and vacuum ultraviolet photoelectron spectra