Stark and Zeeman properties of ozone from molecular beam spectroscopy
Abstract
Stark and Stark-Zeeman transitions within single J states of ozone have been studied using molecular beam electric resonance spectroscopy. Results include dipole moment, μ; dipole moment of the first excited bending mode, μ (010); polarizability anisotropies, αaa-αbb and αaa-αcc; rotational magnetic moments, ga, gb, gc; magnetic susceptibility anisotropies, χaa-χbb and χaa-χcc; and quadrupole moment components, ϑaa, ϑbb, ϑcc. μ=0.5337(1) D, μ (010) =0.5261(1) D, αaa-αbb=2.82(1) Å3, αaa-αcc=2.63(4) Å3, gaa=2.98933(8), gbb=-0.22919(3), gcc=-0.07623(b), χaa-χbb=5.91(2) KHz/kg2, χaa -χcc=12.05(4) KHz/kg2, ϑaa=-1.4(2) ×10-26 esuṡcm2, ϑbb=-0.7(2) ×10-26 esuṡcm2, ϑcc=2.1(3) ×10-26 esuṡcm2.
- Publication:
-
Journal of Chemical Physics
- Pub Date:
- June 1977
- DOI:
- 10.1063/1.433909
- Bibcode:
- 1977JChPh..66.5278M
- Keywords:
-
- 33.55.+c;
- 35.20.My