Normal coordinate treatment of XeO2F2
Abstract
A normal coordinate treatment (NCT) using a modified Urey-Bradley force field (MUBFF) was made for XeO2F2. New analyses were also performed on XeOF4 and XeO3F2. Force constants obtained were compared with force constants from other xenon compounds containing fluorine and/or oxygen atoms. In general, as oxygen atoms are added to XeF2 the bond distance of the Xe-F decreases while the KXeF force constant increases, and the Xe-O bond distances increase while the KXeO force constant decreases.
- Publication:
-
Journal of Chemical Physics
- Pub Date:
- August 1975
- DOI:
- 10.1063/1.431510
- Bibcode:
- 1975JChPh..63.1474W
- Keywords:
-
- 35.20.Dp;
- 63.20.Dj;
- 34.20.Be;
- Phonon states and bands normal modes and phonon dispersion