Fluorination with complex metal fluorides Part III. The fluorination of benzene over potassium hexafluoronickelate(IV)
Abstract
Fluorinations of benzene over potassium hexafluoronickelate(IV) at temperatures of 120-350° have given mixtures of fluorocyclohexanes containing small amounts of fluorocyclohexenes and fluorobenzenes. Benzene was recovered unchanged after contact with potassium trifluoronickelate(II) at elevated temperatures.
- Publication:
-
Journal of Fluorine Chemistry
- Pub Date:
- January 1974
- DOI:
- 10.1016/S0022-1139(00)82626-3
- Bibcode:
- 1974JFluC...3..267P