On a representation of the equation of state of fluids in terms of the adhesive hardspheres model
Abstract
The solution of the model of adhesive hard spheres in the PY approximation is extended to obtain the equation of state for all temperatures, including the condensed and twophases region. A simple scheme is given for the determination of the parameters of the model in terms of empirical data for the second virial coefficient.
 Publication:

Journal of Chemical Physics
 Pub Date:
 October 1974
 DOI:
 10.1063/1.1682475
 Bibcode:
 1974JChPh..61.3194B
 Keywords:

 Adhesion;
 Equations Of State;
 Fluid Dynamics;
 Mathematical Models;
 Condensing;
 Dimensionless Numbers;
 Isothermal Processes;
 Potential Theory;
 Spheres;
 Temperature Effects;
 Vapor Pressure;
 Virial Theorem;
 Thermodynamics and Statistical Physics