Selection rules for pure rotation and vibration‑rotation hyper‑Raman spectra
Abstract
This paper describes a general study of the selection rules for pure rotation and vibrationrotation hyper‑Raman spectra. The investigation encompasses the selection rules for the rotational quantum numbers J, K and M for molecules of any symmetry executing any type of allowed vibration. For molecules in which K is not a good quantum number a parity analysis is described. A complete tabulation of allowed K transitions is given for the common point groups. Coriolis effects and their selection rules for degenerate vibrations are discussed for linear and symmetric rotors.
- Publication:
-
Journal of Raman Spectroscopy
- Pub Date:
- April 1973
- DOI:
- 10.1002/jrs.1250010105
- Bibcode:
- 1973JRSp....1...53S