A complete general valence force field for secondary chlorides
Abstract
A general valence force field for secondary chlorides has been refined which includes torsional force constants based on assignments of low frequency modes in model compounds. This force field also incorporates force constants related to observed intermolecular interactions. The good agreement between observed and calculated frequencies indicates that this force field will be useful in studying the conformation of secondary chlorides.
- Publication:
-
Spectrochimica Acta Part A: Molecular Spectroscopy
- Pub Date:
- December 1973
- DOI:
- 10.1016/0584-8539(73)80061-3
- Bibcode:
- 1973AcSpA..29.2025M