Nonempirical investigation of the probability for radiationless transitions. I
Abstract
The probability for radiationless T1-S0-transitions was investigated. An expression for the Franck-Condon factor is obtained by means of exact integration, on the basis of the theory of multiphonon transitions. This expression is utilized for the investigation of the radiation-less T1-S0-transition in the formaldehyde molecule. It is found that the transition mentioned does not play a large role.
- Publication:
-
Soviet Physics Journal
- Pub Date:
- November 1971
- DOI:
- 10.1007/BF00823835
- Bibcode:
- 1971SvPhJ..14.1484S