Raman spectra and vibrational assignments for 1,1,1-trihaloethanes and their deuterium derivatives
Abstract
Raman spectra of the first three members of the 1,1,1-trihaloethane series, CH 3CX 3, X = F, Cl, Br, were obtained for the liquids under low resolution. All but two active fundamental vibrational frequencies were observed, and for most bands it was possible to make a qualitative determination of the depolarization ratio. The completely deuterated compounds were synthesized and their spectra also were examined. Normal coordinate calculations were carried out to confirm the proposed assignments.
- Publication:
-
Journal of Molecular Spectroscopy
- Pub Date:
- April 1970
- DOI:
- 10.1016/0022-2852(70)90072-X
- Bibcode:
- 1970JMoSp..34...33S