SpinSpin Interaction in Paramagnetic Ions
Abstract
Expressions for the intraatomic spinspin interaction parameter ρ for the Hund'srule ground state are given in terms of the radial integrals M^{k}. These integrals occur also in the spinotherorbit and orbitorbit interactions. Using previously obtained values of the M^{k}, the expressions for ρ are evaluated for a number of p, d, and fshell ions. Comparison with results of Pryce for 3d ions shows that his estimates were too large by as much as an order of magnitude.
 Publication:

Physical Review
 Pub Date:
 August 1965
 DOI:
 10.1103/PhysRev.139.A1209
 Bibcode:
 1965PhRv..139.1209W