Coulomb Gauge in Non-Relativistic Quantum Electro-Dynamics and the Shape of Spectral Lines

An examination is made of the Green dyadic for the propagation functions of non-relativistic quantum electrodynamics in the Coulomb gauge div A = 0. The existence of false precursors is shown to be associated with singularities at the origin in certain momentum space representations of the propagators and this allows a prescription to be given to eliminate such precursors. This prescription is proved equivalent to an exact consideration of the near fields associated with quantum transitions. The analogous treatment for the state vectors in decaying systems is carried through and is applied in detail to the problems of the shape of natural spectral lines and the transition rate for stimulated emission. It is shown that the expected line shape for the Lamb 1057 Mc/s line in hydrogen is Lorentzian within the context of Lamb's experiments-intensity against Zeeman splitting energy. This is in contradiction to the predictions of Arnous and Heitler. The distribution in k (circular frequency) for a natural line, on the other hand, has a factor k³ times the resonant denominator. The definitive position between the conflicting transition rates in the literature is given. The relationship of the calculations to a gauge-independent Hamiltonian, considered in the paper, is investigated in detail. This Hamiltonian, transformed canonically from the conventional one, is shown to be valid for internal, dynamical, quantized electromagnetic fields; its analogue in the case of external applied fields being well known. It is demonstrated that the transformation eliminates many of the difficulties associated with the false near fields and that it also allows certain radiative effects, where the atom acts as a whole, to be computed in a straight-forward manner.