Two-dimensional van der Waals ferromagnetic thin film CrTe2 with high Curie temperature and metallic conductivity

Two-dimensional van der Waals (2D vdW) materials have opened up an opportunity to explore an innovative spin-based magnetic nanodevice. However, controllable fabrication of 2D vdW ferromagnets with high Curie temperature remains challenging. In this paper, we reported the growth of 2D CrTe₂ single-crystal films epitaxially on Al₂O₃ substrates using pulsed laser deposition. We find that it shows a typical paramagnetic-ferromagnetic (PM-FM) phase transition around 200 K. The precise Curie temperature and Weiss temperature are 189 and 206.7 K, respectively. The saturation magnetization reaches 73.64 emu/g for the film thickness of 30 nm. The critical exponent β = 0.329 indicates that the magnetic interactions obey the 3D-Ising model. Electronic transport measurement confirms that a CrTe₂ film always remains a metallic behavior at 5 K ≤ T ≤ 320 K and the resistivity of room temperature is 1.5 mΩ/cm. The first-principles calculation uncovers that the FM ordering state mainly stems from an exchange coupling of the adjacent Cr-spin t_2g polarized electrons and the metallic conductivity is due to p-d orbital hybridization between Cr and Te atoms. This work would shed new light on studying large-scale growth of 2D magnets and developing 2D magnet-based nanodevices of room temperature.