Heavy metal pollution in groundwater of urban Delhi environs: Pollution indices and health risk assessment

The excess presence of heavy metals in water resources deteriorates the quality and has a high potential for bioaccumulation and environmental contamination. The study of heavy metals in water is essential because of their integration in the food chain and the potential for sublethal effects on aquatic and human life. To understand the extent of heavy metal pollution, a total of 64 groundwater samples (32 in each pre-and post-monsoon season) were collected around the Yamuna River's flood plains in the Delhi region. In this study, pollution indices and health risk assessment methodologies were used to estimate the significant threat to humans. In examined seasons, the sequence of heavy metal content in groundwater is Fe > Mn > Zn > B > As>Ni > Pb. The heavy metal pollution index (HPI) revealed that in the pre-and post-monsoon seasons, 53% and 44% (HPI >100), of groundwater samples are at high-risk zone respectively. 53% of pre-monsoon and 56% of post-monsoon samples were found highly polluted, according to the degree of contamination (C_d). Moreover, health risk assessment shows that hazard index (HI) values for heavy metals were found significantly high (HI >1) in groundwater samples inferring increased non-cancerous risk to the local community. The results imply that continuous exposure can lead to chronic diseases in the population residing in the study region. In both carcinogenic and non-carcinogenic assessments, children's hazard index and carcinogenic risk assessment (CR) scores were found higher. As a result, compared to adults in the study region, children are more vulnerable to potential health threats. The principal component analysis (PCA) method was used to figure out the origin of heavy metals, and it was found that As, Fe, Mn, and Zn come from non-anthropogenic sources, whereas mixed sources (natural and anthropogenic) may be responsible for B, Ni, and Pb presence. The results of the study will help to develop an effective strategy for environmental assessment and monitoring to control groundwater pollution of the Delhi urban environs.