Anthropogenic processes drive heterogeneous distributions of toxic elements in shallow groundwater around a smelting site

Smelting activities have a far-reaching influence on the quality of soil and groundwater, while most studies have neglected the information on the pollution characteristics of groundwater. The hydrochemical parameters of shallow groundwater and the spatial distributions of toxic elements were investigated in this study. Correlations analysis and groundwater evolution revealed that the major ions were primarily determined by silicate weathering and calcite dissolution process, and anthropogenic processes had a significant effect on groundwater hydrochemistry. Almost 79%, 71%, 57%, 89%, 100%, and 78.6% of samples exceeded the standards of Cd, Zn, Pb, As, SO₄^2-, and NO₃^-, and their distribution is closely related to the production process. Analysis of soil geochemistry indicated that the relatively mobile forms of toxic elements strongly influence the origin and concentration in shallow groundwater. Besides, rainfall with high magnitude would lead to a decrease of toxic elements in shallow groundwater, whereas the area once stacked waste residue was the opposite. It is recommended to strengthen risk management of the limited mobility fraction while devising a plan for waste residue treatment in accordance with the local pollution conditions. The research on controlling the mechanism of toxic elements in shallow groundwater, along with sustainable development in the study area and other smelting zones may benefit from this study.