Modified metal-organic frameworks as photocatalysts
Abstract
Photocatalysis is a promising and ideal technology to utilize solar energy for energy regeneration and environmental remediation. Photocatalysis based on metal-organic frameworks (MOFs) has attracted extensive attention because of their excellent properties such as tunable structure and optical properties. This review principally summarizes the progress of various modification strategies, including decoration of organic linker or metal center, combination with semiconductors and metal nanoparticles loading. applied to different MOFs (mainly UiOs, MILs, and ZIFs), and their specific applications were summarized as well. In addition, the existing problems and the development prospect of MOFs for photocatalysis were also presented.
- Publication:
-
Applied Catalysis B: Environmental
- Pub Date:
- September 2018
- DOI:
- 10.1016/j.apcatb.2018.03.039
- Bibcode:
- 2018AppCB.231..317Q
- Keywords:
-
- MOF;
- metal-organic framework;
- UiO;
- University of Oslo;
- MIL;
- Materials of Institut Lavoisier;
- ZIF;
- zeolitic imidazolate framework;
- VB;
- valence band;
- CB;
- conduction band;
- HOMO;
- highest occupied molecular orbital;
- LUMO;
- lowest unoccupied molecular orbital;
- UV;
- ultraviolet;
- UV-vis;
- ultraviolet-visible;
- OG;
- orange G;
- RhB;
- rhodamine B;
- RBBR;
- Remazol Brilliant Blue R;
- MB;
- methylene blue;
- MO;
- methyl orange;
- ErB;
- Erythrosin B;
- Rh6G;
- rhodamine 6G;
- DRS;
- diffuse reflective spectra;
- DOS;
- density of states;
- LMCT;
- ligand-to-metal charge transfer;
- BDC;
- terephthalic acid;
- MNP;
- metal nanoparticle;
- GR;
- graphene;
- RGO;
- reduced graphene oxide;
- SBU;
- secondary building unites;
- PC;
- pyridinecarboxaldehyde;
- PSE;
- post-synthetic exchange;
- DFT;
- density functional theory;
- ESR;
- electron spin resonance;
- ATA;
- 2-aminoterephthalic acid;
- CNNS;
- carbon nitride nanosheet;
- PANI;
- polyaniline;
- SPR;
- surface plasmon resonance;
- PCVG;
- photochemical vapor generation;
- PHIK;
- heptazine imide;
- AC;
- acetylacetone;
- CoIIIBr2(LH);
- co-dioxime-diimine;
- MOCVD;
- metal-organic chemical vapor deposition;
- POM;
- polyoxometalate;
- PPCP;
- pharmaceutical and personal care product;
- MAG-MIL;
- magnetic MIL-53(Fe);
- TEOA;
- triethanolamine;
- NC;
- nanocube;
- PEC;
- photoelectrochemical;
- OER;
- oxygen evolution reaction;
- BP;
- black phosphous;
- PMS;
- peroxymonosulfate;
- TEM;
- transmission electron microscope;
- SEM;
- scanning electron microscope