Metamorphism in the Martian crust

Compositions of basaltic and ultramafic rocks analyzed by Mars rovers and occurring as Martian meteorites allow predictions of metamorphic mineral assemblages that would form under various thermophysical conditions. Key minerals identified by remote sensing roughly constrain temperatures and pressures in the Martian crust. We use a traditional metamorphic approach (phase diagrams) to assess low-grade/hydrothermal equilibrium assemblages. Basaltic rocks should produce chlorite + actinolite + albite + silica, accompanied by laumontite, pumpellyite, prehnite, or serpentine/talc. Only prehnite-bearing assemblages have been spectrally identified on Mars, although laumontite and pumpellyite have spectra similar to other uncharacterized zeolites and phyllosilicates. Ultramafic rocks are predicted to produce serpentine, talc, and magnesite, all of which have been detected spectrally on Mars. Mineral assemblages in both basaltic and ultramafic rocks constrain fluid compositions to be H₂O-rich and CO₂-poor. We confirm the hypothesis that low-grade/hydrothermal metamorphism affected the Noachian crust on Mars, which has been excavated in large craters. We estimate the geothermal gradient (>20 °C km^-1) required to produce the observed assemblages. This gradient is higher than that estimated from radiogenic heat-producing elements in the crust, suggesting extra heating by regional hydrothermal activity.